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Sapphirine occurs in three associations: (i) fine-grained subhedral mineral associated with quartz enclosed in garnet, (ii) intergrowth with Al-rich orthopyroxene (up .. Brown M.Ultra-high-temperature metamorphism and multistage decompressional evolution of sapphirine granulites from the Palni hill ranges, southern India.
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So, in concrete, there would be reaction between quartz and the alkaline compounds of the concrete, typically Ca(OH)2, if the proportion of amorphous or cryptocrystalline (very fine crystalline) quartz increases. It leads to the formation of silica gels in concrete and as you know the silica gel attracts water, swells and cracks.
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Preservation of amorphous ultrafine material: A proposed proxy for .
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Spinel + Quartz UHT assemblage in Kerala khondalites, southern India .. The thin flakes and disseminations within the khondalite bands represent the conversion of biogenic material trapped within host sediments during high grade metamorphism as indicated ... are in turn surrounded by coronas of cordierite from ultra-.